reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis. Asymmetric induction was introduced by Hermann Emil Fischer...

effect, change in electron density Asymmetric induction, preferring one stereoisomer over another Grammar induction Inductive bias Inductive probability...

through interactions at the transition state. This biasing is known as asymmetric induction and can involve chiral features in the substrate, reagent, catalyst...

carbonyl groups. The catalysts were found to afford high levels of asymmetric induction in several processes, including the ene reaction of ethyl glyoxylate...

"Preparation of an Optically Active Prostaglandin Intermediate via Asymmetric Induction". J. Am. Chem. Soc. 97 (23): 6908–6909. doi:10.1021/ja00856a074....

used in Sharpless asymmetric dihydroxylation While the presence of any symmetry element within a ligand intended for asymmetric induction might appear counterintuitive...

Sharpless asymmetric dihydroxylation (also called the Sharpless bishydroxylation) is the chemical reaction of an alkene with osmium tetroxide in the presence...

in particular Rh2[(S)-DOSP]4 and Rh2[(S)-BPTV]4 can induce modest asymmetric induction and was used to synthesize the antifungal agent pseudolaric acid...

chiral auxiliaries and chiral catalysts, and the application of asymmetric induction. The use of enzymes (biocatalysis) may also produce the desired compound...

Asymmetric hydrogenation is a chemical reaction that adds two atoms of hydrogen to a target (substrate) molecule with three-dimensional spatial selectivity...

Asymmetric induction in allylic alkylations." J. Am. Chem. Soc. 1973, 95, 8200–8201. doi:10.1021/ja00805a056. Trost, B. M.; Strege, P. E. "Asymmetric...

= OR*). (1) Asymmetric versions of the above reaction have taken advantage of a number of strategies for achieving asymmetric induction. The highest...

structure. He also did work in stereochemistry and Cram's rule of asymmetric induction is named after him. In 1973, Cram collaborated on research with Irish...

2010. Other chiral additives can be used as the initial source of asymmetric induction, with the major product of that first reaction being rapidly amplified...

employing chiral starting materials have been used to effect either asymmetric induction or simple diastereoselection (1) After carbanion formation, the [2...

predictable stereodirecting effects resulting in high levels of asymmetric induction. Racemization of the newly created carbon-nitrogen stereo center...

(June 1981). "Asymmetric Total Synthesis of Erythromycin. 1. Synthesis of an Erythronolide A Seco Acid Derivative via Asymmetric Induction". Journal of...

potential application is its use as a temporary substituent promoting asymmetric induction for example in this diastereoselective one-pot reaction involving...

transfer of an H2 molecule from the reductant to the substrate. Asymmetric induction in transition metal catalyzed reactions is achieved through the use...

rearrangement Coupling reaction Crabbé reaction Craig method Cram's rule of asymmetric induction Creighton process Criegee reaction Criegee rearrangement Cross metathesis...

insertions are seen. Both inter- and intra-molecular insertions admit asymmetric induction from a chiral metal catalyst. Carbenes can form adducts with nucleophiles...

also played a large role in the establishment of the concept of asymmetric induction and the ability to predict the stereochemistry of reactions controlled...

(3 January 2014). "Foldamer-Mediated Remote Stereocontrol: >1,60 Asymmetric Induction" (PDF). Angewandte Chemie International Edition. 53 (1): 151–155...

one enantiomer or diastereomer over the other is formally known as asymmetric induction. In this kind of Lewis acid, the electron-accepting atom is typically...

Etter, Jeffrey B. (1987). "Lanthanides in organic synthesis. 8. 1.3-Asymmetric induction in intramolecular Reformatskii-type reactions promoted by samarium...

organolithium species can be obtained through asymmetric metalation of prochiral substrates. Asymmetric induction requires the presence of a chiral ligand...

et al. (1981). "Asymmetric total synthesis of erythromcin. 1. Synthesis of an erythronolide A secoacid derivative via asymmetric induction". J. Am. Chem...

chiral chemical synthesis, and specifically of the phenomenon of asymmetric induction during nucleophilic attack at hindered carbonyl centers (see the...

discrimination between these possible enantiomers that requires asymmetric induction. Torquoselectivity is also used to describe selective electrocyclic...

bulky tosyl group on the imine electrophile is responsible for the asymmetric induction taking place. In another application DOM is applied in placing a...