• Thumbnail for Diastereomeric recrystallization
    Diastereomeric recrystallisation is a method of chiral resolution of enantiomers from a racemic mixture. It differs from asymmetric synthesis, which aims...
    3 KB (420 words) - 15:13, 30 January 2023
  • Thumbnail for Diastereomer
    different sides of the plane (anti). The names are derived from the diastereomeric four-carbon aldoses erythrose and threose. These prefixes are not recommended...
    9 KB (1,089 words) - 04:06, 15 April 2024
  • Thumbnail for Cis-Dichlorobis(ethylenediamine)cobalt(III) chloride
    of the d-α-bromocamphor-π-sulfonate salt. The diastereomeric salts are separated by recrystallization. After their purification, the individual diastereomers...
    5 KB (296 words) - 21:17, 7 March 2024
  • Thumbnail for Enders SAMP/RAMP hydrazone-alkylation reaction
    strain. Little and coworkers obtained the alkylated hydrazone in diastereomerically pure form (de > 95%) through the Enders' alkylation reaction. This...
    23 KB (2,515 words) - 15:15, 4 April 2024
  • Thumbnail for Ethyl cyanohydroxyiminoacetate
    in virtually quantitative yield. The compound can be purified by recrystallization from ethanol or ethyl acetate. Compared with the benzotriazole derivatives...
    9 KB (898 words) - 19:41, 20 December 2023
  • Thumbnail for Trans,trans,trans-(1,5,9-Cyclododecatriene)nickel(0)
    be leveraged to separate the t-Ni(cdt) enantiomers with recrystallization of diastereomeric 18-electron t-Ni(cdt)L* complexes (where L* = optically active...
    7 KB (549 words) - 17:48, 29 February 2024
  • Thumbnail for Tramadol
    (1S,2S)-isomer from the diastereomeric minor racemate [(1R,2S)-isomer and (1S,2R)-isomer] is realized by the recrystallization of the hydrochlorides. The...
    96 KB (9,009 words) - 07:06, 11 April 2024
  • tert-butylhydroperoxide; this led to the formation of a 4:1 mixture of diastereomeric epoxides, favoring the desired isomer in which attack had occurred from...
    17 KB (2,031 words) - 09:46, 7 April 2024
  • tetracarboxylic acid, separation of an enantiomer by selective recrystallization of diastereomeric salts, amide bond formation, and crystallization of purified...
    14 KB (1,420 words) - 21:55, 12 March 2023