Diphosphane, or diphosphine, is an inorganic compound with the chemical formula P2H4. This colourless liquid is one of several binary phosphorus hydrides...
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like rotting fish, due to the presence of substituted phosphine and diphosphane (P2H4). With traces of P2H4 present, PH3 is spontaneously flammable in...
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bioluminescence or chemiluminescence, caused by the oxidation of phosphine (PH3), diphosphane (P2H4) and methane (CH4), produced by organic decay. The term "will-o'-the-wisp"...
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States Department of Energy facilities Petroleum hydrocarbon (PHC) sludge Diphosphane Metalorganics of main group metals (e.g. aluminium, gallium, indium,...
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(PH3), diphosphane (P2H4), and methane (CH4). These compounds, produced by organic decay, can cause photon emissions. Since phosphine and diphosphane mixtures...
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significantly more readily, indicative of particularly strong hydrogen bonding. Diphosphane and hydrogen disulfide exhibit only weak hydrogen bonding and have little...
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functionalities, but such ligands often lead to coordination polymers. A diphosphane linked with pentamethylene was claimed to span across a square planar...
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Related compounds Other anions Tetrafluorohydrazine Hydrogen peroxide Diphosphane Diphosphorus tetraiodide Other cations Organic hydrazines Related Binary...
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of the Carbomethoxy Cycle for the Carboalkoxylation of Ethene by Pd–Diphosphane Catalysts". Angew. Chem. Int. Ed. 43 (1): 90–94. doi:10.1002/anie.200352369...
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mixed-valence compounds and very unstable +VI oxidation state. In hydrazine, diphosphane, and organic derivatives of the two, the nitrogen or phosphorus atoms...
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Saame, Jaan; Kütt, Agnes; Leito, Ivo (2012). "Basicity of Phosphanes and Diphosphanes in Acetonitrile". European Journal of Organic Chemistry. 2012 (11): 2167–2172...
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Space-filling model dinitrogen hydride hydrazine (diazane) N2H4 diphosphorus hydride diphosphine (diphosphane) P2H4 diarsenic hydride diarsine (diarsane) As2H4...
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e.g. calcium phosphide (often produced together with small amount of diphosphane) Arsine from arsenides, e.g. zinc arsenide Stibine from antimonides,...
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of the Carbomethoxy Cycle for the Carboalkoxylation of Ethene by Pd–Diphosphane Catalysts". Angew. Chem. Int. Ed. 43 (1): 90–94. doi:10.1002/anie.200352369...
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unsolved. This challenge was solved with precatalysts of the type RuCl2(diphosphane)(diamine). These catalysts preferentially reduce ketones and aldehydes...
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Ammonia Hydrazine Diazene Triazene Tetrazene Pentazole Hexazine Phosphine Diphosphane Triphosphane Diphosphene Hexaphosphabenzene Arsine Diarsane Triarsane...
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halides phosphorus trifluoride phosphorus pentafluoride Related compounds diphosphane diphosphines Except where otherwise noted, data are given for materials...
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M. van Leeuwen (2003). "SPANphos: A C2-Symmetric trans-Coordinating Diphosphane Ligand". Angewandte Chemie International Edition. 42 (11): 1322–1325...
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"Synthesis and Molecular Modeling Studies of SYNPHOS®, a New, Efficient Diphosphane Ligand For Ruthenium-Catalyzed Asymmetric Hydrogenation". Eur. J. Org...
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photolysis of P4, and in the presence of 2,3-dimethyl-1,3-butadiene the diphosphane resulting from Diels–Alder addition is again formed. To date, no direct...
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are: HOOH, dioxidane (hydrogen peroxide is an acceptable name) H2PPH2, diphosphane H3SiSiH2SiH2SiH3, tetrasilane The recommendations describe three ways...
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M. Van Leeuwen (2003). "SPANphos: A C2-Symmetric trans-Coordinating Diphosphane Ligand". Angewandte Chemie. 42 (11): 1322–1325. doi:10.1002/anie.200390330...
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Christine; Börner, Armin (2003-01-01). "Chiral Oxo- and Oxy-Functionalized Diphosphane Ligands Derived from Camphor for Rhodium(I)-Catalyzed Enantioselective...
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Related Binary Phosphorus halides phosphorus triiodide Related compounds diphosphane diphosphines Except where otherwise noted, data are given for materials...
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compounds Other anions triazane Related Binary phosphanes phosphane diphosphane Related compounds triazene Except where otherwise noted, data are given...
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Demay, S.; Volant, F.; Knochel, P. (2001). "New C2-Symmetrical 1,2-Diphosphanes for the Efficient Rhodium-Catalyzed Asymmetric Hydroboration of Styrene...
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such as lithium aluminum hydride can reduce diphosphene to give stable diphosphanes: ArP = PAr + AlH → ArHP − PHAr {\displaystyle {\ce {ArP=PAr\ +\ AlH\rightarrow...
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