• The E1cB elimination reaction is a type of elimination reaction which occurs under basic conditions, where the hydrogen to be removed is relatively acidic...
    17 KB (2,139 words) - 16:36, 25 March 2024
  • Thumbnail for Elimination reaction
    third type of reaction, E1CB, exists. Finally, the pyrolysis of xanthate and acetate esters proceed through an "internal" elimination mechanism, the...
    14 KB (1,843 words) - 07:43, 4 February 2024
  • Thumbnail for Chemical reaction
    participation of a base. Because of the similar conditions, both reactions in the E1 or E1cb elimination always compete with the SN1 substitution. The E2 mechanism...
    66 KB (7,964 words) - 01:34, 7 April 2024
  • Thumbnail for Pyridyne
    E1cB-elimination reaction. Pyridynes were first postulated by Levine and Leake in 1955. In 1969 Zoltewicz and Nisi trapped 3,4-pyridyne in a reaction...
    4 KB (444 words) - 22:36, 6 April 2023
  • Boord olefin synthesis (category Olefination reactions)
    reaction with magnesium forming an intermediate Grignard reagent. The alkoxy group is a poor leaving group and therefore an E1cB elimination reaction...
    2 KB (209 words) - 19:34, 27 October 2022
  • cyclization reaction Elimination reaction Beta elimination Cope elimination E1cB elimination reaction Hofmann elimination Organic redox reaction Cannizzaro...
    8 KB (576 words) - 12:14, 30 October 2023
  • Thumbnail for Organic reaction
    Organic reactions are chemical reactions involving organic compounds. The basic organic chemistry reaction types are addition reactions, elimination reactions...
    14 KB (1,182 words) - 23:43, 15 February 2024
  • expansion reaction Duff reaction Dutt–Wormall reaction Dyotropic reaction E1cB elimination reaction Eder reaction Edman degradation Eglinton reaction Ehrlich–Sachs...
    38 KB (3,433 words) - 17:07, 5 January 2024
  • Thumbnail for Aldol condensation
    the product to an enolate, which eliminates via the E1cB mechanism, while dehydration in acid proceeds via an E1 reaction mechanism. Depending on the nature...
    17 KB (1,679 words) - 06:32, 22 March 2024
  • Thumbnail for Enolase
    overall mechanism for converting 2-PG to PEP is proposed to be an E1cB elimination reaction involving a carbanion intermediate. The following detailed mechanism...
    30 KB (3,252 words) - 21:54, 3 March 2024
  • via a mechanism wherein methanesulfonyl chloride first undergoes an E1cb elimination to generate the highly reactive parent sulfene (CH2=SO2), followed...
    9 KB (772 words) - 03:36, 2 February 2024
  • Thumbnail for Leaving group
    Leaving group (category Reaction mechanisms)
    mechanism in elimination reactions. With poor leaving groups, the E1cB mechanism is favored, but as the leaving group's ability changes, the reaction shifts...
    22 KB (2,532 words) - 15:42, 14 February 2024
  • Thumbnail for Fujimoto–Belleau reaction
    followed by an E1cB elimination of hydroxide occurs. The Fujimoto–Belleau reaction is used in commonly used in steroid synthesis. The reaction can be employed...
    3 KB (263 words) - 17:32, 2 January 2024
  • elimination event proceeds in two steps, deprotonation, followed by expulsion of the nucleophile. Thus, the process is formally analogous to the E1cb...
    26 KB (2,936 words) - 17:42, 27 March 2024
  • Thumbnail for Adenylosuccinate lyase
    enzyme that catalyzes two reactions in the de novo purine biosynthetic pathway. In both reactions it uses an E1cb elimination reaction mechanism to cleave fumarate...
    20 KB (2,387 words) - 03:01, 22 December 2023
  • Thumbnail for Enoyl-CoA hydratase
    intermediate is identical to that which would be generated from an E1cB-elimination reaction. ECH is mechanistically similar to fumarase. "EC 4.2.1.17". www...
    5 KB (1,036 words) - 16:50, 31 December 2023
  • Thumbnail for Nucleophilic aromatic substitution
    Nucleophilic aromatic substitution (category Reaction mechanisms)
    pathways. SNAr (addition-elimination) mechanism aromatic SN1 mechanism encountered with diazonium salts benzyne mechanism (E1cB-AdN) free radical SRN1 mechanism...
    11 KB (1,262 words) - 11:16, 17 April 2024
  • Thumbnail for Argininosuccinate lyase
    form fumarate and arginine, occurs through an E1cb elimination reaction. The base initiates the reaction by deprotonating the carbon adjacent to the arginine...
    13 KB (1,497 words) - 13:12, 26 August 2023
  • Thumbnail for Glycolysis
    2-phosphoglycerate to phosphoenolpyruvate. This reaction is an elimination reaction involving an E1cB mechanism. Cofactors: 2 Mg2+, one "conformational"...
    81 KB (8,782 words) - 03:47, 9 April 2024
  • Thumbnail for Phenylalanine ammonia-lyase
    deprotonation by a basic residue. The carbanion intermediate of this E1cB-elimination reaction, which is stabilized by partial positive regions in the active...
    20 KB (2,162 words) - 08:47, 30 October 2023
  • Thumbnail for Succinate dehydrogenase
    transfer step. Thereafter, there are two possible elimination mechanisms: E2 or E1cb. In the E2 elimination, the mechanism is concerted. The basic residue...
    24 KB (2,682 words) - 23:06, 29 February 2024
  • O’Ferrall, R. A. (1970). "Relationships between E2 and E1cB mechanisms of beta-elimination". J. Chem. Soc. B: 274–277. doi:10.1039/J29700000274. Jencks, William...
    8 KB (976 words) - 10:30, 21 April 2020
  • Thumbnail for Fumarase
    through an acid-base catalyzed elimination by means of a carbanionic intermediate, meaning it proceeds as E1cB elimination (Figure 1). The function of fumarase...
    13 KB (1,474 words) - 20:09, 27 October 2023
  • Thumbnail for Entner–Doudoroff pathway
    2-phosphoglycerate to phosphoenolpyruvate. This reaction is an elimination reaction involving an E1cB mechanism. Cofactors: 2 Mg2+: one "conformational"...
    18 KB (2,106 words) - 04:58, 5 February 2024
  • Thumbnail for List of vacuum tubes
    4671/E1C (955) – Indirectly heated Acorn triode 4672/E1F (954) – Indirectly heated Acorn pentode 4674 – Indirectly heated Acorn diode 4675 – 4671/E1C with...
    329 KB (40,570 words) - 19:13, 31 March 2024