Hydrogen–deuterium exchange (also called H–D or H/D exchange) is a chemical reaction in which a covalently bonded hydrogen atom is replaced by a deuterium...
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Deuterium (hydrogen-2, symbol 2H or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other is protium, or hydrogen-1)....
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Heavy water (redirect from Deuterium oxide)
Heavy water (deuterium oxide, 2 H 2O, D 2O) is a form of water whose hydrogen atoms are all deuterium (2 H or D, also known as heavy hydrogen) rather than...
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no neutron. Deuterium thus has about twice the atomic mass as normal hydrogen. Heavy water consists of water molecules with two deuterium atoms instead...
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techniques to study protein structure and function (especially hydrogen–deuterium exchange), and his definitions of protein primary, secondary, tertiary...
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specific. Thus, it can distinguish between hydrogen and deuterium. The amide protons in the protein exchange readily with the solvent, and, if the solvent...
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of activating C-H bonds by oxidative addition as seen through hydrogen/deuterium exchange, involved in the insertion of phosphines, and capable of forming...
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monitored by difference Fourier-transform infrared spectroscopy and hydrogen/deuterium exchange". Biochemical Journal. 382 (Pt 1) (Pt 1 ed.): 121–129. doi:10...
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Tritium (redirect from Hydrogen-3)
the common isotope hydrogen-1 (protium) contains one proton and zero neutrons, and that of a non-radioactive hydrogen-2 (deuterium) contains one proton...
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distribution and relative abundance of hydrogen isotopes. There are two stable isotopes of hydrogen, protium 1H and deuterium 2H, which vary in relative abundance...
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thermonuclear bomb, Ivy Mike, used liquid deuterium, also known as Hydrogen-2, for nuclear fusion. The product of hydrogen combustion in a pure oxygen environment...
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Alpha helix (section Geometry and hydrogen bonding)
of a random coil (although these might be discerned by, e.g., hydrogen-deuterium exchange). Finally, cryo electron microscopy is now capable of discerning...
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the other stable hydrogen isotope, is known as deuterium and contains one proton and one neutron in the nucleus. Nearly all deuterium in the universe is...
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Kinetic isotope effect (redirect from Deuterium isotope effect)
frequencies of the affected bonds. For instance, changing a hydrogen atom (H) to its isotope deuterium (D) represents a 100% increase in mass, whereas in replacing...
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Nations Office for the Coordination of Humanitarian Affairs Hydrogen–deuterium exchange Lisofylline, an experimental anti-inflammatory drug Pro Tools HDX...
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2020). "Residual Structure of Unfolded Ubiquitin as Revealed by Hydrogen/Deuterium-Exchange 2D NMR". Biophysical Journal. 119 (10): 2029–38. doi:10.1016/j...
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Isotopic labeling (redirect from Deuterium labeling)
deuterium for the hydrogen is observed in phenol's hydroxyl group (resulting in C6H5OD), indicating that phenol readily undergoes hydrogen-exchange reactions...
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as hydrogen or deuterium, into the plasma. This process results in the ionization of hydrogenic atoms the excitation of ions through charge exchange, as...
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in part using D2 (deuterium), because recovered alkenes often contain deuterium. For aromatic substrates, the first hydrogenation is slowest. The product...
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covalent bond. If we neglect the small proportion of deuterium and tritium which may be present, each hydrogen atom consists of one proton and one electron....
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Grocholska, Paulina; Bąchor, Remigiusz (2021-05-18). "Trends in the Hydrogen−Deuterium Exchange at the Carbon Centers. Preparation of Internal Standards for...
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Krystek SR, Huang RY, Wei H, Tao L, Lin Z, et al. (April 2015). "Hydrogen/deuterium exchange mass spectrometry applied to IL-23 interaction characteristics:...
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proteins and peptides. In 2000s Topp introduced solid-state hydrogen-deuterium exchange as the method for stability characterization of lyophilized biopharmaceutical...
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to be in the hydrogen sulfide, resulting in excess deuterium in the hydrogen sulfide relative to the cold tower. For n moles of deuterium per mole of protium...
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Daniel J.; Shen, Jacob; Klopman, Gilles (1975). "Onium ions. XVI. Hydrogen-deuterium exchange accompanying the cleavage of ammonium (tetradeuterioammonium)...
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active sites of metal catalysts. Such catalysts are used in hydrogen-deuterium exchange, hydrogenolysis, and isomerization reactions. It is well suited...
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probe the solvent accessibility of various parts of the protein. Hydrogen-deuterium exchange mass spectrometry has been used to study proteins and their conformations...
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In electrochemistry, the standard hydrogen electrode (abbreviated SHE), is a redox electrode which forms the basis of the thermodynamic scale of oxidation-reduction...
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(residues 1–117) is conferred by its structural flexibility. Hydrogen/deuterium exchanges analysis indicates that allosteric binding of Phe globally alters...
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so that they are readily cleaved by proteases, undergo rapid hydrogen-deuterium exchange and exhibit a small dispersion (<1 ppm) in their 1H amide chemical...
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