Isotopomers or isotopic isomers are isomers which differ by isotopic substitution, and which have the same number of atoms of each isotope but in a different...
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labeled atoms and unlabeled atoms in one compound represent isotopomers. By measuring the isotopomer distribution of the differently labeled metabolites, the...
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For example, CH3CHDCH3 and CH3CH2CH2D are a pair of structural isotopomers. Isotopomers should not be confused with isotopologues, which are chemical species...
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Structural isomer (section Structural isotopomers)
) And, in both cases, the 1,2-dideutero structural isotopomer would occur as two stereo isotopomers, cis and trans. Two molecules (including polyatomic...
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isotopically modified element, the term isotopomer, first proposed by Seeman and Paine in 1992, is used. Isotopomerism is analogous to constitutional isomerism...
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Isomer (section Isotopomers)
each element were replaced by a single isotope, they are described as isotopomers or isotopic isomers. In the above two examples if all D {\displaystyle...
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an anti-cancer therapy or for scintigraphy (medical imaging). It is an isotopomer of lutetium(III) chloride containing the radioactive isotope 177Lu, which...
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chemical elements Bainbridge mass spectrometer Geotraces Isotope hydrology Isotopomer List of nuclides List of particles Mass spectrometry Reference materials...
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abundances across the globe. In high-resolution mass spectrometry the mass isotopomers 12C1H4 and 13C1H4 are observed as distinct molecules, with molecular...
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Brown; K. Liu; R. J. Saykally (1997). "Pseudorotation in Water Trimer Isotopomers Using Terahertz Laser Spectroscopy". J. Phys. Chem. A. 101 (48): 9032...
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"Non-invasive assessment of hepatic mitochondrial metabolism by positional isotopomer NMR tracer analysis (PINTA)". Nature Communications. 8 (1): 798. Bibcode:2017NatCo...
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It is an umbrella term for the more specific terms isotopologue and isotopomer, coined by Jan Kaiser and Thomas Röckmann in 2008. Toyoda, Sakae; Yoshida...
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between the two metabolic pathways can be studied by using 13C-glucose isotopomers. In higher plants, the MEP pathway operates in plastids while the mevalonate...
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"On the Effective Temperature of Sunspot Umbrae using Beryllium Hydride Isotopomer Lines", Sangeetha, R.; Sriramachandran, P.; Bagare, S. P.; Rajamanickam...
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Sinskey, Anthony J.; Stephanopoulos, Gregory (1999). "Metabolite and isotopomer balancing in the analysis of metabolic cycles: II. Applications" (PDF)...
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In these cases, the observed spectrum is the sum of spectra for each isotopomer. One of the great conveniences of NMR spectroscopy for organic molecules...
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receptors are capable of distinguishing between deuterated and undeuterated isotopomers of cyclopentadecanone by vibrational energy level sensing. However this...
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(1998). "Separation of Closely Boiling Isomers and Identically Boiling Isotopomers via Electron-Transfer-Assisted Extraction". Analytical Chemistry. 70...
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to rotation with P Q and R branches. The R branch is very weak in H3 isotopomer but strong with D3 (trideuterium). The symmetric stretch vibration mode...
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kcal/mol barrier[clarification needed]. The lifetime of the deuterium isotopomer is predicted to be much longer due to a greater difficulty of tunneling...
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and a successor to MS-Deconv. It groups top-down spectral peaks into isotopomer envelopes and converts them to monoisotopic neutral masses. In addition...
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effects are determined through complementary studies on a series of isotopomers. Accordingly, it is quite useful to combine hydrogen isotope effects...
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charges. Additional information, such as the mass spacing between mass isotopomers or the relationship between multiple charge states, is required to assign...
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and W. J. Riley, (2010), Mathematical treatment of isotopologue and isotopomer speciation and fractionation in biochemical kinetics, Geochim. Cosmochim...
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bromofluoromethane is regulated due to its ozone depletion potential (0.73). Its isotopomer CH2Br18F contains fluorine-18 (18F) and is used in radiochemistry. Debrominating...
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Emmenegger, Lukas; Sigrist, Markus W. (2008-06-06). "Determination of N_2O isotopomers with quantum cascade laser based absorption spectroscopy". Optics Express...
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steady-state, two conditions that assume that metabolite concentrations and isotopomer distributions are not changing over time, respectively. Knowledge of the...
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clear portion of the atmospheric window, as well as having numerous isotopomers also available for easy study, and in addition to having a large dipole...
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response to Turin's 2013 paper, involving deuterated and undeuterated isotopomers of the musk cyclopentadecanone, Block et al. in a 2015 paper in PNAS...
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et al. (December 2016). "Asymmetric Induction by a Nitrogen 14 N/15 N Isotopomer in Conjunction with Asymmetric Autocatalysis". Angewandte Chemie. 55 (49):...
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