• Thumbnail for Keggin structure
    The Keggin structure is the best known structural form for heteropoly acids. It is the structural form of α-Keggin anions, which have a general formula...
    13 KB (1,635 words) - 18:50, 5 March 2024
  • Thumbnail for Polyoxometalate
    was characterized by X-ray crystallography 1934. This structure is called the Keggin structure after its discoverer. The 1970's witnessed the introduction...
    32 KB (3,338 words) - 08:12, 9 May 2024
  • Thumbnail for Heteropolymetalate
    recur. The Keggin ion for example is common to both molybdates and tungstates with diverse central heteroatoms. The Keggin and Dawson structures have...
    9 KB (765 words) - 07:53, 9 May 2024
  • Thumbnail for Phosphotungstic acid
    (Pauling) The structure was determined by J.F Keggin first published in 1933 and then in 1934 and is generally known as the Keggin structure. The anion has...
    20 KB (2,141 words) - 01:11, 15 December 2023
  • Thumbnail for Silicotungstic acid
    of the mixture with hydrochloric acid. The polyoxo cluster adopts a Keggin structure, with Td point group symmetry. Silicotungstic acid is an irritating...
    5 KB (333 words) - 11:37, 17 February 2024
  • and Laden to show that the material is based on Al13 units with a Keggin ion structure and that this base unit then undergoes complex transformations to...
    8 KB (885 words) - 09:40, 11 April 2024
  • Thumbnail for Dawson structure
    three missing octahedra. As in Keggin structures, the Dawson structure has an oxyanion at its core. Unlike Keggin structures, there are two such anions,...
    1 KB (179 words) - 07:21, 18 January 2024
  • Thumbnail for Phosphomolybdic acid
    Retrieved 2018-10-06. Dias, J. A.; Dias, S. C. L.; Caliman, E. (2014). "Keggin Structure Polyoxometalates". Inorganic Syntheses: Volume 36. Inorganic Syntheses...
    5 KB (300 words) - 17:09, 22 August 2022
  • Thumbnail for Molybdenum blue
    silicon and arsenic. The heteropoly-molybdenum blues have structures based on the Keggin structure. The blue colour arises because the near-colourless anion...
    17 KB (2,195 words) - 18:17, 22 September 2023
  • Thumbnail for Ammonium phosphomolybdate
    José Alves; Dias, Sílvia Cláudia Loureiro; Caliman, Ednéia (2014). "Keggin Structure Polyoxometalates". Inorganic Syntheses: Volume 36. Vol. 36. pp. 210–217...
    4 KB (148 words) - 05:12, 9 May 2024
  • atoms. This results in 3-dimensional structures called polyoxometalates. Typical examples occur in the Keggin structure of the phosphomolybdate ion. Edge...
    18 KB (2,163 words) - 14:46, 8 April 2024
  • Kegginite (section Structure)
    the Keggin anion as the basis of the structural unit. It also recognizes the work of J.F. Keggin who first experimentally described the structure of the...
    5 KB (435 words) - 18:49, 18 March 2024
  • Thumbnail for Molybdenum
    Molybdenum (category Chemical elements with body-centered cubic structure)
    solid, which adopts a polymeric structure. Molybdenum(V) chloride MoCl5 dark green solid, which adopts a dimeric structure. Molybdenum(VI) chloride MoCl6...
    71 KB (8,065 words) - 17:21, 16 May 2024
  • Thumbnail for Chromium compounds
    tetrahedral coordination of chromium(III) has been reported for the Cr-centered Keggin anion [α-CrW12O40]5–. Chromium(III) hydroxide (Cr(OH)3) is amphoteric, dissolving...
    14 KB (1,400 words) - 20:36, 19 December 2023
  • Thumbnail for Carbonate ester
    of Dimethyl Carbonate from Methanol and Carbon Dioxide over Co1.5PW12O40 Keggin-Type Heteropolyanion". International Journal of Molecular Sciences. 11 (4):...
    12 KB (1,314 words) - 05:09, 9 March 2024
  • Thumbnail for Formic acid
    aqueous catalytic partial oxidation of wet biomass by the OxFA process. A Keggin-type polyoxometalate (H5PV2Mo10O40) is used as the homogeneous catalyst...
    38 KB (3,909 words) - 11:41, 25 March 2024
  • Thumbnail for Chromium
    Chromium (category Chemical elements with body-centered cubic structure)
    tetrahedral coordination of chromium(III) has been reported for the Cr-centered Keggin anion [α-CrW12O40]5–. Chromium(III) hydroxide (Cr(OH)3) is amphoteric, dissolving...
    99 KB (11,258 words) - 16:48, 13 May 2024
  • Thumbnail for Tungsten
    Tungsten (category Chemical elements with body-centered cubic structure)
    as a symmetric cluster of twelve tungsten-oxygen octahedra known as the Keggin anion. Many other polyoxometalate anions exist as metastable species. The...
    78 KB (8,830 words) - 21:54, 6 May 2024
  • Thumbnail for List of minerals recognized by the International Mineralogical Association
    Ophirite (IMA2013-017) is a mineral with a heteropolytungstate tri-lacunary keggin anion. Melcherite (IMA2015-018) and peterandresenite (IMA2012-084) have...
    46 KB (5,009 words) - 02:38, 14 October 2023
  • aqueous solution: correlations between the "Core-links" model and "Cage-like" Keggin-Al13 model". Coord. Chem. Rev. 248 (5–6): 441–455. doi:10.1016/j.ccr.2003...
    33 KB (3,163 words) - 09:39, 11 April 2024
  • Thumbnail for Aluminium compounds
    formation of hydroxide bridges, forming many oligomeric ions, such as the Keggin ion [Al13O4(OH)24(H2O)12]7+. The process ends with precipitation of aluminium...
    25 KB (2,804 words) - 09:39, 11 April 2024
  • Thumbnail for Achim Müller
    Jean-Philippe; Maestre, Juan-M; Poblet, Josep-M (December 1998). "From Lindqvist and Keggin ions to electronically inverse hosts". Coordination Chemistry Reviews. 178–180:...
    29 KB (3,021 words) - 05:02, 11 March 2024