Oppenauer oxidation, named after Rupert Viktor Oppenauer [de], is a gentle method for selectively oxidizing secondary alcohols to ketones. The reaction...

isopropoxide is used in MPV reductions of ketones and aldehydes and the Oppenauer oxidation of secondary alcohols. In these reactions, it is assumed that the...

Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters...

oxidation Sulfonium-based oxidation of alcohols to aldehydes Pyridinium chlorochromate Jones oxidation Oppenauer oxidation Pfitzner–Moffatt oxidation...

reactions. Alcohol oxidation Pyridinium chlorochromate Jones oxidation Oppenauer oxidation Pfitzner–Moffatt oxidation Parikh–Doering oxidation Albright-Goldman...

reduction. This method, however, has the ability to undergo the reverse Oppenauer oxidation due to the proximity of the two reagents. Thus the reaction runs...

hydrogenation Olefin isomerization Olefin oxidation Olefin polymerization Oppenauer oxidation Oxidation Oxidative addition Oxidative decarbonylation Oxygenation Oxymercuration...

reagent Olefin metathesis Oppenauer oxidation Ostromyslenskii reaction, Ostromisslenskii reaction Overman rearrangement Oxidative decarboxylation Oxo synthesis...

to the Oppenauer oxidation, which favors the oxidation of secondary alcohols over primary and several other specialty oxidations. Over-oxidation of primary...

to give α-hydroxy ketones Meerwein–Ponndorf–Verley reduction and Oppenauer oxidation - related interconversions of ketones and secondary alcohols via...

to the dioxirane using oxone. It serves as an oxidizing agent in Oppenauer oxidation. Trifluoracetone is also used in a synthesis of 2-trifluoromethyl-7-azaindoles...

equation and, for example, the Meerwein–Ponndorf–Verley reduction/Oppenauer oxidation equilibrium for the measurement of axial versus equatorial values...

reaction Cannizzaro reaction Meerwein–Ponndorf–Verley reduction Oppenauer oxidation Seki, Tsunetake; Nakajo, Tetsuo; Onaka, Makoto (2006). "The Tishchenko...

to the corresponding ketone). Selective oxidation of alcohols to aldehydes requires circumventing over-oxidation to the carboxylic acid. One popular approach...

Nucleophilic epoxidation Oppenauer oxidation Prilezhaev reaction Rubottom oxidation Schmidt reaction Swern oxidation Wacker-Tsuji oxidation Reduction Birch reduction...

hydrogenation), followed by oxidation with benzophenone in presence of potassium tert butoxide or aluminium tert butoxide (Oppenauer oxidation). The 6 ketone group...

heteroaromatic substrates tend to fail. Meerwein–Ponndorf–Verley reduction Oppenauer oxidation Dehydrogenation Hydrogenation Hydrogenolysis Borrowing hydrogen Wang...

as also occurs for the first step in the synthesis of nandrolone. Oppenauer oxidation then transforms the C17β hydroxyl group into a ketone functionality...

of enones, as well as other Lewis acid-catalyzed reactions like Oppenauer oxidation and Meerwein-Pondorf-Verley reductions. . A number of metallasilsesquioxanes...

produced chiral 28 and on Oppenauer oxidation chiral 29. Hydrogenation (Adams' catalyst) gave alcohol 30, chromic acid oxidation gave ketone 31, sodium borohydride...

cheap oxygen is the oxidant of choice. For sensitive substrates, Oppenauer transfer oxidation avoids overoxidation to a carboxylic acid. When a mixture of...

Firstly, the double bond in ring D is hydrogenated, followed by Oppenauer oxidation of the hydroxyl group and the concurrent migration of the remaining...

Subsequent acetylation with acetic anhydride and tosyl acid followed by Oppenauer oxidation afforded 17a-acetoxy- progesterone (95) in good yield (115). Tests...

ring (10). The product is saponified and then the subject of an Oppenauer oxidation, which is then dehydrogenated to the 4,6-diene with chloranil (11)...

Library. Retrieved October 22, 2017. Arrich, Jasmin; Schütz, Nikola; Oppenauer, Julia; Vendt, Janne; Holzer, Michael; Havel, Christof; Herkner, Harald...