Triphenylphosphine (IUPAC name: triphenylphosphane) is a common organophosphorus compound with the formula P(C6H5)3 and often abbreviated to PPh3 or Ph3P...
18 KB (1,624 words) - 10:29, 1 March 2024
Wilkinson's catalyst (redirect from Rhodium(I) tris(triphenylphosphine) chloride)
rhodium(III) chloride hydrate with an excess of triphenylphosphine in refluxing ethanol. Triphenylphosphine serves as both a ligand and a two-electron reducing...
13 KB (1,209 words) - 06:07, 24 February 2024
Triphenylphosphine oxide (often abbreviated TPPO) is the organophosphorus compound with the formula OP(C6H5)3, also written as Ph3PO or PPh3O (Ph = C6H5)...
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Tetrakis(triphenylphosphine)palladium(0) (sometimes called quatrotriphenylphosphine palladium) is the chemical compound [Pd(P(C6H5)3)4], often abbreviated...
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Dichlorotris(triphenylphosphine)ruthenium(II) is a coordination complex of ruthenium. It is a chocolate brown solid that is soluble in organic solvents...
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Triphenylphosphine selenide is an organophosphorus compound with the formula (C6H5)3PSe. It is a white solid which is soluble in most organic solvents...
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Bis(triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands. It is a...
8 KB (594 words) - 02:40, 3 January 2024
Triphenylphosphine sulfide (IUPAC name: triphenyl-λ5-phosphanethione) is the organophosphorus compound with the formula (C6H5)3PS, usually written Ph3PS...
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Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium is the organoruthenium half-sandwich compound with formula RuCl(PPh3)2(C5H5). It as an air-stable...
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Vaska's complex (redirect from Iridium(I)bis(triphenylphosphine))
the trivial name for the chemical compound trans-carbonylchlorobis(triphenylphosphine)iridium(I), which has the formula IrCl(CO)[P(C6H5)3]2. This square...
9 KB (812 words) - 19:34, 14 March 2022
Dichlorobis(triphenylphosphine)nickel(II) refers to a pair of metal phosphine complexes with the formula NiCl2[P(C6H5)3]2. The compound exists as two isomers...
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Bis(triphenylphosphine)iminium chloride is the chemical compound with the formula [((C6H5)3P)2N]Cl, often abbreviated [(Ph3P)2N]Cl, where Ph is phenyl...
7 KB (591 words) - 01:05, 3 September 2023
Triphenylphosphine phenylimide is the organophosphorus compound with the formula Ph3P=NPh (Ph = C6H5). It is a white solid that is soluble in organic solvents...
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Triphenylphosphine dichloride, (C6H5)3PCl2, is a chlorinating agent widely used in organic chemistry. Applications include the conversion of alcohols and...
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TPPTS (redirect from Sulfonated triphenylphosphine)
(abbreviated TPPTS), is an organic compound that is also known as sodium triphenylphosphine trisulfonate. The compound has the formula P(C6H4SO3Na)3. This white...
7 KB (749 words) - 14:48, 28 February 2024
Chloro(triphenylphosphine)gold(I) or triphenylphosphinegold(I) chloride is a coordination complex with the formula (Ph3P)AuCl. This colorless solid is...
8 KB (581 words) - 00:32, 11 December 2023
alcohol into a variety of functional groups, such as an ester, using triphenylphosphine and an azodicarboxylate such as diethyl azodicarboxylate (DEAD) or...
15 KB (1,570 words) - 00:13, 10 March 2024
Phosphonium (redirect from Triphenylphosphine dibromide)
produced by alkylation of organophosphines. For example, the reaction of triphenylphosphine with methyl bromide gives methyltriphenylphosphonium bromide: PPh3...
13 KB (1,231 words) - 23:45, 1 June 2023
Zeise's salt (redirect from Ethylenebis(triphenylphosphine)platinum(0))
other ethylene complexes have been prepared. For example, ethylenebis(triphenylphosphine)platinum(0), [(C6H5)3P]2Pt(H2C=CH2), wherein the platinum is three-coordinate...
9 KB (842 words) - 14:20, 10 April 2024
(Triphenylphosphine)iron tetracarbonyl is a coordination complex with the formula Fe(CO)4(PPh3) (Ph = C6H5). An off-white solid, this complex is derived...
3 KB (195 words) - 09:26, 11 January 2024
isomer is obtained with isomerization free catalysts such as rhodium-triphenylphosphine complexes. The use of the cobalt complex leads by isomerization of...
25 KB (3,102 words) - 23:30, 27 November 2023
other palladium compounds and complexes. Palladium(II) acetate plus triphenylphosphine is used as a catalyst in organic synthesis. Coordination compounds...
6 KB (555 words) - 05:48, 25 March 2024
Bis(triphenylphosphine)platinum chloride is a metal phosphine complex with the formula PtCl2[P(C6H5)3]2. Cis- and trans isomers are known. The cis isomer...
4 KB (316 words) - 05:58, 24 February 2024
Tricarbonylbis(triphenylphosphine)iron(0) is a coordination complex with the formula Fe(CO)3(PPh3)2 (Ph = C6H5). A yellow solid, this complex is derived...
4 KB (312 words) - 11:24, 20 February 2024
Mitsunobu reaction, where it serves as an oxidizer of triphenylphosphine to triphenylphosphine oxide. It has also been used to generate aza-Baylis-Hillman...
4 KB (190 words) - 22:07, 22 March 2022
reduced by triphenylphosphine to bis(triphenylphosphine)palladium(0) (1) concomitant with oxidation of triphenylphosphine to triphenylphosphine oxide. Step...
13 KB (1,355 words) - 19:29, 15 December 2023
Carbonyl hydrido tris(triphenylphosphine)rhodium(I) [Carbonyl(hydrido)tris(triphenylphosphane)rhodium(I)] is an organorhodium compound with the formula...
6 KB (557 words) - 06:10, 24 February 2024
Hydridotetrakis(triphenylphosphine)rhodium(I) is the coordination complex with the formula HRh[P(C6H5)3]4. It consists of a Rh(I) center complexed to four...
3 KB (177 words) - 03:30, 4 September 2023
Bis(triphenylphosphine)rhodium carbonyl chloride is the organorhodium complex with the formula [RhCl(CO)(PPh3)2]. This complex of rhodium(I) is a bright...
4 KB (276 words) - 22:35, 2 June 2023
Chloro(triphenylphosphine)gold(I), which features 2-coordinate metal centre....
19 KB (2,209 words) - 15:27, 22 January 2024